The binding energy and Thermodynamic Parameters of cis- Platinum Di Ammino Chlorine (cis- [Pt(NH3)2Cl]+) and trans- Platinum Di Ammino Chlorine (trans- [Pt(NH3)2Cl]+) complexes with Guanine has been studied by density functional theory (DFT) calculations in water. The binding energies (Ebin) of cis- and trans-[Pt(NH3)2ClG]+ are calculated to be 79.38 kcal/mol and 74.98 kcal/mol, respectively. The binding energy (Ebin) of cis-[Pt(NH3)2ClG]+ turns out to be energetically more favorable by about 1.88 kcal/mol than the trans-[Pt(NH3)2Cl]+. At the point of thermodynamic, the formation of cis-[Pt(NH3)2ClG]+ (aq) with G (Solv) equal to -10.36 kcal/mol is more favorable than trans-[Pt(NH3)2ClG]+ (aq) with 16.21 kcal/mol.
Nikmaram, F. R., & Ahmadi, M. K. (2014). Thermodynamic Parameters of Cis-Platin and Trans-Platin Complexes with Guanine in Water, A DFT Study. Journal of Physical & Theoretical Chemistry, 10(4), 211-214.
MLA
F. R. Nikmaram; M. Khan Ahmadi. "Thermodynamic Parameters of Cis-Platin and Trans-Platin Complexes with Guanine in Water, A DFT Study". Journal of Physical & Theoretical Chemistry, 10, 4, 2014, 211-214.
HARVARD
Nikmaram, F. R., Ahmadi, M. K. (2014). 'Thermodynamic Parameters of Cis-Platin and Trans-Platin Complexes with Guanine in Water, A DFT Study', Journal of Physical & Theoretical Chemistry, 10(4), pp. 211-214.
VANCOUVER
Nikmaram, F. R., Ahmadi, M. K. Thermodynamic Parameters of Cis-Platin and Trans-Platin Complexes with Guanine in Water, A DFT Study. Journal of Physical & Theoretical Chemistry, 2014; 10(4): 211-214.
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